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Selectfluor and alcohol-mediated synthesis of bicyclic oxyfluorination compounds by Wagner-Meerwein rearrangement

dc.contributor.authorDagalan, Ziya
dc.contributor.authorCelikoglu, Muhammed Hanifi
dc.contributor.authorCelik, Saffet
dc.contributor.authorKocak, Ramazan
dc.contributor.authorNisanc, Bilal
dc.date.accessioned2025-03-28T07:22:40Z
dc.date.available2025-03-28T07:22:40Z
dc.date.issued2024
dc.identifier.issn1860-5397
dc.identifier.urihttps://doi.org/10.3762/bjoc.20.129
dc.identifier.urihttps://hdl.handle.net/20.500.12450/5826
dc.description.abstractHerein, we report the first environmentally friendly systematic fluoroalkoxylation reactions in bicyclic systems. New oxyfluorination products were obtained with excellent yields (up to 98%) via Wagner-Meerwein rearrangement using benzonorbornadiene and the chiral natural compound (+)-camphene as bicyclic alkenes, selectfluor as an electrophilic fluorine source, and water and various alcohols as nucleophile sources. The structure of bicyclic oxy- and alkoxyfluorine compounds was determined by NMR and QTOFMS analyses.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [2209-A]; YOK 100/2000; TUBITAK BIDEB 2211A programen_US
dc.description.sponsorshipM.H.C. and B.N are grateful to The Scientific and Technological Research Council of Turkey (TUBITAK) (Project number 2209-A) for financial support. Ziya Dagalan thanks to YOK 100/2000 and TUBITAK BIDEB 2211A program for their support.en_US
dc.language.isoengen_US
dc.publisherBeilstein-Instituten_US
dc.relation.ispartofBeilstein Journal of Organic Chemistryen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectalkoxyfluorine compoundsen_US
dc.subjectbicyclic alkeneen_US
dc.subjectoxyfluorinationen_US
dc.subjectselectfluoren_US
dc.subjectWagner-Meerwein rearrangementen_US
dc.titleSelectfluor and alcohol-mediated synthesis of bicyclic oxyfluorination compounds by Wagner-Meerwein rearrangementen_US
dc.typearticleen_US
dc.departmentAmasya Üniversitesien_US
dc.authoridCelik, Saffet/0000-0002-4225-2471
dc.authoridKOCAK, Ramazan/0000-0002-5016-2767
dc.authoridNisanci, Bilal/0000-0003-4290-1539
dc.identifier.volume20en_US
dc.identifier.startpage1462en_US
dc.identifier.endpage1467en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopus2-s2.0-85199451095en_US
dc.identifier.doi10.3762/bjoc.20.129
dc.department-temp[Dagalan, Ziya; Celikoglu, Muhammed Hanifi; Kocak, Ramazan; Nisanc, Bilal] Ataturk Univ, Fac Sci, Dept Chem, Erzurum, Turkiye; [Celik, Saffet] Trakya Univ, Technol Res Dev Applicat & Res Ctr, Edirne, Turkiye; [Kocak, Ramazan] Amasya Univ, Fac Arts & Sci, Dept Chem, Amasya, Turkiyeen_US
dc.identifier.wosWOS:001260328600001en_US
dc.identifier.pmid38978745en_US
dc.snmzKA_WOS_20250328
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US


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